Atropisomeric Chiral Diiododienes (Z,Z)‑2,3-Di(1-iodoalkylidene)tetralins: Synthesis, Enantiomeric Resolution, and Application in Asymmetric Catalysis
收藏Figshare2017-07-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Atropisomeric_Chiral_Diiododienes_i_Z_i_i_Z_i_2_3-Di_1-iodo_alkylidene_tetralins_Synthesis_Enantiomeric_Resolution_and_Application_in_Asymmetric_Catalysis/5225194
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资源简介：
The C2-symmetric tetralin-fused 1,4-diiodo-1,3-butadiene derivatives, (Z,Z)-2,3-di(1-iodoalkylidene)tetralin 1a–c, are atropisomeric and can be resolved into the two persistent axially chiral enantiomers by HPLC on a chiral stationary phase. The enantiomerically pure compounds can serve as chiral organocatalysts for dearomatizing spirolactonization to show good performance in up to 73% ee.
创建时间：
2017-07-20
