Heterobimetallic Carbene Complexes by a Single-Step Site-Selective Metalation of a Tricarbene Ligand
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https://figshare.com/articles/dataset/Heterobimetallic_Carbene_Complexes_by_a_Single_Step_Site_Selective_Metalation_of_a_Tricarbene_Ligand/2428960
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资源简介：
The unsymmetrical tris(imidazolium)
salt H3-1(Br)3, featuring a 1,2,4-substitution
pattern of the central
phenyl ring, after triple imidazolium C2 deprotonation reacts in a
one-pot reaction with Pd(OAc)2 and [M(Cp*)(Cl)2]2 (M = RhIII, IrIII) to yield heterobimetallic
complexes [3] (M = Rh) and [4] (M = Ir),
in which the PdII ion is chelated by two ortho N-heterocyclic
carbene (NHC) donors while the third NHC donor coordinates to the
MIII center, which orthometalates the central phenyl ring.
创建时间：
2016-02-19
