A Formal Synthesis of Ionomycin Featuring a Permanganate-Mediated Oxidative Cyclisation
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http://www.thieme-connect.com/DOI/DOI?10.1055/s-0030-1258327
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资源简介：
Key steps in a synthesis of the C17-C32 fragment of
ionomycin are (a) an auxiliary-directed oxidative cyclisation
of a diene with potassium permanganate to construct a tetrahydrofuran
ring and four stereogenic centres in a single operation, and (b)
a chain-appendage reaction featuring the alkylation of an enolsilane
by an oxocarbenium ion generated from a 2-phenylsulfonyl-substituted tetrahydrofuran.
提供机构：
Georg Thieme Verlag, Stuttgart, New York
创建时间：
2011-11-30
