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Biomimetic Synthesis of Zeylanone and Zeylanone Epoxide by Dimerization of 2‑Methyl-1,4-naphthoquinone

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Biomimetic_Synthesis_of_Zeylanone_and_Zeylanone_Epoxide_by_Dimerization_of_2_Methyl_1_4_naphthoquinone/2427274
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A biomimetic synthesis of zeylanone and zeylanone epoxide, which are natural dimeric naphthoquinones, has been accomplished starting from plumbagin, a natural monomeric naphthoquinone. The key features of our synthesis are cascade intermolecular and intramolecular Michael reactions, followed by epoxidation of the resultant hydroquinone with molecular oxygen.
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2016-02-19
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