N-Heterocyclic “Pincer” Dicarbene Complexes of Cobalt(I), Cobalt(II), and Cobalt(III)
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https://figshare.com/articles/dataset/N_Heterocyclic_Pincer_Dicarbene_Complexes_of_Cobalt_I_Cobalt_II_and_Cobalt_III_/3321451
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资源简介：
The complex Co(C−N−C)Br2 (C−N−C = 2,6-bis(arylimidazol-2-ylidene)pyridine, aryl = 2,6-Pri2C6H3),
prepared by aminolysis of Co[N(SiMe3)2]2 with the
corresponding imidazolium salt (CH−N−CH)Br2, was
methylated to the square-planar Co(C−N−C)(CH3) and
oxidized with BrN(SiMe3)2 to give Co(C−N−C)Br3. The
Co(I), Co(II), and Co(III) complexes show no ethylene
polymerization activity.
创建时间：
2016-05-06
