Investigations into an Anionic Oxy-Cope/Transannular Conjugate Addition Approach to 7,20-Diisocyanoadociane
收藏Figshare2016-02-16 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Investigations_into_an_Anionic_Oxy_Cope_Transannular_Conjugate_Addition_Approach_to_7_20_Diisocyanoadociane/2257819
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资源简介：
An anionic oxy-Cope/transannular conjugate addition approach to the potent antimalarial 7,20-diisocyanoadociane is presented. The unexpected formation of undesired diastereomers in the key reaction led to the structural reassignment of previous products of this type of cascade and a reevaluation of the reversibility of the transannular ring closure. During efforts to coax the reaction toward the desired product, a transannular ene reaction provided tricyclic compounds relevant to the kempane diterpenoids.
创建时间：
2016-02-16
