The reaction of [Ti4(OMe)14Cl2] (1) with an excess of AlMe3 gave the cocrystallite [Ti2(μ-OMe)2(μ-Cl)Cl3(thf)3]·[Ti2(μ-OMe)3Cl3(thf)3] (2·3) species in a 1:1 ratio. Similar to 2, [Ti2(μ-OEt)2(μ-Cl)Cl3
Addition of 1 equiv of TlCp to compound [(TiCl2)2(μ-{(η5-C5Me4SiMeO)2(μ-O)})] (A) at 80 °C gave a mixture with different molar ratios of the two possible isomers of [(TiClCp)(TiCl2)(μ-{(η5-C5Me4SiMeO)