A Bridging Selenoacyl Complex via Alkynylselenolatoalkylidyne Rearrangement
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https://figshare.com/articles/dataset/A_Bridging_Selenoacyl_Complex_via_Alkynylselenolatoalkylidyne_Rearrangement/2778088
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资源简介：
The alkynylselenolatoalkylidyne complex [Mo(C−Se−CCSiMe3)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) reacts with [RhCl(PPh3)3] via an unusual C−Se bond cleavage/formation sequence to provide the heterodinuclear bridging selenoacyl complex [MoRh(μ⊥-SeCCCSiMe3)Cl(CO)2(PPh3){HB(pzMe2)3}], the crystal structure of which reveals a RhMoCSe tetrahedrane core.
创建时间：
2010-04-12
