Three-Coordinate, Cyclic Bent Allene Iron Complexes
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https://figshare.com/articles/dataset/Three_Coordinate_Cyclic_Bent_Allene_Iron_Complexes/2415967
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资源简介：
Novel
three-coordinate Fe complexes featuring 1,2-diphenyl-3,5-bis(2,6-dimethylphenoxy)pyrazolin-4-ylidine
or “cyclic bent allene” (CBA) have been synthesized.
Reaction with FeCl2(PPh3)2 results
in the loss of both phosphines to yield monomeric Fe(CBA)Cl2. Treatment with 2 equiv of benzyl Grignard affords the three-coordinate
alkylated product Fe(CBA)(Bn)2. Exposure of the alkylated
species to an atmosphere of CO results in reductive elimination of
1,3-diphenylpropanone and formation of trigonal-bipyramidal Fe(CBA)(CO)4.
创建时间：
2016-02-19
