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One-Pot Synthesis of Diaryl 1,2-Diketones via Zn-Mediated Reductive Coupling

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Figshare2022-10-13 更新2026-04-28 收录
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https://figshare.com/articles/dataset/One-Pot_Synthesis_of_Diaryl_1_2-Diketones_via_Zn-Mediated_Reductive_Coupling/21330516
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A reductive coupling reaction was established for the synthesis of diaryl 1,2-dicarbonyl compounds from aryl methyl ketones in good yields. The mechanistic study showed the reaction undergoes C(CO)–C(sp3) bond cleavage, with the reductive coupling reaction occurring through an electron transfer process. Notably, the reaction not only is simple to operate but also has mild reaction conditions and a wide range of applicable substrates.
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2022-10-13
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