Synthesis of Large Polycyclic Aromatic Hydrocarbons from Bis(biaryl)acetylenes: Large Planar PAHs with Low π-Sextets
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下载链接：
https://figshare.com/articles/dataset/Synthesis_of_Large_Polycyclic_Aromatic_Hydrocarbons_from_Bis_biaryl_acetylenes_Large_Planar_PAHs_with_Low_Sextets/2618467
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资源简介：
A new synthesis of large PAHs with low Clar sextets was developed. This synthesis involves initial bis(biaryl)acetylene 1, which undergoes initial ICl-aromatization and a subsequent Mizoroki–Heck coupling reaction to give dibenzochrysene derivative 3 that can be transformed into planar PAHs 4 using DDQ-oxidation.
创建时间：
2011-09-02
