Enantioselective Oxidative Ring-Opening Reaction of Aziridines with α‑Nitroesters Using Cinchona Alkaloid Amide/Nickel(II) Catalysts
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https://figshare.com/articles/dataset/Enantioselective_Oxidative_Ring-Opening_Reaction_of_Aziridines_with_Nitroesters_Using_Cinchona_Alkaloid_Amide_Nickel_II_Catalysts/4452719
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资源简介：
The enantioselective
oxidative ring-opening reaction of aziridines
with α-nitroacetates has been developed. Good yields and enantioselectivity
were observed for the reaction of various aziridines using a novel
cinchona alkaloid amide/NiBr2 catalyst. Both enantiomers
of products could be obtained by using pseudoenantiomeric chiral catalysts.
This process offers an efficient route for the synthesis of α-aminoketones.
创建时间：
2016-12-15
