Catalytic C–C Bond Formation Promoted by Organo- and Amidomagnesium(II) Compounds
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https://figshare.com/articles/dataset/Catalytic_C_C_Bond_Formation_Promoted_by_Organo_and_Amidomagnesium_II_Compounds/2367169
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Mg(mesC{NCy}2)(N{SiMe3}2)(THF) is a (pre)catalyst for C–C bond formation. Attempted isolation of intermediates in a proposed catalytic cycle was hindered by facile ligand redistribution. A subsequent investigation of commercially available organo- or amidomagnesium(II) compounds (including Grignard reagents) demonstrated similar catalytic behavior.
创建时间：
2016-02-18
