Highly Selective Ring Expansion of Bicyclo[3.1.0]hexenes
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https://figshare.com/articles/dataset/Highly_Selective_Ring_Expansion_of_Bicyclo_3_1_0_hexenes/4010781
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A Ru-carbene-promoted ring expansion of bicyclo[3.1.0]hexenes with terminal alkynes is reported. The reaction delivers seven-membered carbocycles starting from readily available starting materials and was found to be highly regioselective. The resulting seven-membered ring products contain both conjugated diene and cyclopropane substructures that could be selectively reacted in subsequent transformations.
创建时间：
2016-10-17
