Pseudotetrahedral d<sup>0</sup>, d<sup>1</sup>, and d<sup>2</sup> Metal−Oxo Cores within a Tris(alkoxide) Platform
收藏NIAID Data Ecosystem2026-03-06 收录
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Low-coordinate first-row metal complexes of d0 [vanadium(V)], d1 [chromium(V)], and d2 [chromium(IV)] assume the unusual ligand field of a pseudotetrahedron when supported by a tripodal tBu2(Me)CO− alkoxide framework. Structural, spectroscopic, and reactivity studies, supported by density functional theory calculations, indicate that the d electrons in the chromium(V) and -(IV) oxo complexes reside in metal−oxygen antibonding orbitals, engendering disparate reactivity of the metal−oxo, depending on the number of d electrons present.
创建时间：
2016-02-24
