Imino Sulfinamidines: Synthesis and Coordination Chemistry of a Novel Class of Chiral Bidentate Ligands

The new imino sulfinamidine ligand PhS(NHt-Bu)NC(Me)N(C6H3-2,6-iPr2), LH (11) was synthesized from N-(2,6-diisopropylphenyl)acetamidine (9) and N-tert-butyl phenylsulfinimidoyl chloride (10). Reaction of LH (11) with ZnEt2
or AlMe3 gave the complexes LZnEt (12) and LAlMe2 (13), respectively. The structures of 12 and 13 were determined
by X-ray diffraction and were shown to contain L as a κ2-N1,N5 bidentate ligand in a six-membered chelate. Formation
of the magnesium complex (LMgN(TMS)2·L2Mg) (14) from 11, MgI2, and KN(SiMe3)2 highlighted a secondary
coordination mode of L, binding through the sulfinamidine nitrogens in a four-membered chelate.