Approach to Vicinal t‑Boc-amino Dibromides via Catalytic Aminobromination of Nitrostyrenes without Using Chromatography and Recrystallization
收藏Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Approach_to_Vicinal_i_t_i_Boc_amino_Dibromides_via_Catalytic_Aminobromination_of_Nitrostyrenes_without_Using_Chromatography_and_Recrystallization/2447683
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资源简介：
A 1.0 mol % amount of K3PO4·3H2O was found to catalyze aminohalogenation reaction of nitrostyrenes with N,N-dibromo-tert-butylcarbamate (t-Boc-NBr2) in a dichloroethane system. Good to excellent yields and complete regioselectivity have been achieved by taking advantage of the GAP workup without using traditional purification techniques such as column chromatography and recrystallization. A new mechanism is proposed involving radical and ionic catalytic cycles and an intramolecular migration.
创建时间：
2016-02-20
