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Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with H2O2, Catalyzed by Aminopyridine Manganese Complexes

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Highly_Efficient_Regioselective_and_Stereospecific_Oxidation_of_Aliphatic_C_H_Groups_with_H_sub_2_sub_O_sub_2_sub_Catalyzed_by_Aminopyridine_Manganese_Complexes/2489452
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Aminopyridine manganese complexes [LMnII(OTf)2] having a similar coordination topology catalyze the oxidation of unactivated aliphatic C–H groups with H2O2, demonstrating excellent efficiency (up to TON = 970), site selectivity, and stereospecificity (up to >99%).
创建时间:
2016-02-20
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