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Straightforward Access to the [3.2.2]Nonatriene Structural Framework via Intramolecular Cyclopropenation/Buchner Reaction/Cope Rearrangement Cascade

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NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/Straightforward_Access_to_the_3_2_2_Nonatriene_Structural_Framework_via_Intramolecular_Cyclopropenation_Buchner_Reaction_Cope_Rearrangement_Cascade/2194120
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资源简介:
A one-pot cascade process of benzyl enoldiazoacatates, initiated by dirhodium­(II)-catalyzed intramolecular cyclopropene formation, occurs via a subsequent Buchner reaction and Cope rearrangement to provide straightforward access to bicyclo[3.2.2]­nonatriene derivatives in high yields and selectivities.
创建时间:
2016-02-14
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