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Straightforward Access to the [3.2.2]Nonatriene Structural Framework via Intramolecular Cyclopropenation/Buchner Reaction/Cope Rearrangement Cascade

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NIAID Data Ecosystem2026-03-08 收录
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A one-pot cascade process of benzyl enoldiazoacatates, initiated by dirhodium­(II)-catalyzed intramolecular cyclopropene formation, occurs via a subsequent Buchner reaction and Cope rearrangement to provide straightforward access to bicyclo[3.2.2]­nonatriene derivatives in high yields and selectivities.

创建时间:
2016-02-14
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