Flash Communication: Ring-Opening of Biphenylene with Magnesium(I) and Magnesium–Dinitrogen Complexes
收藏Figshare2026-04-28 收录
下载链接：
https://figshare.com/articles/dataset/_i_Flash_Communication_i_Ring-Opening_of_Biphenylene_with_Magnesium_I_and_Magnesium_Dinitrogen_Complexes/29663026
下载链接
链接失效反馈官方服务：
资源简介：
Rare examples of reductive C–C single bond cleavages using main group metal complexes have been achieved in reactions between biphenylene and a magnesium–dinitrogen complex and an anionic magnesium(I) compound, [K2{Mg(EtNONTCHP)}2(μ-N2)] and [K{Mg(EtNONTrip)}]2 (EtNONTCHP and EtNONTrip = bulky bis(anilido)xanthenes), respectively. In the products, [K2{Mg(EtNONAr)}2(μ-C12H8)] (Ar = TCHP or Trip), the reduced biphenyldiyl ligand [C12H8]2–, bridges two Mg centers through its 2,2′-positions.
