A Bridging Side-on Allenylidene Dimolybdenum Complex without Carbonyl Stabilization
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https://figshare.com/articles/dataset/A_Bridging_Side_on_Allenylidene_Dimolybdenum_Complex_without_Carbonyl_Stabilization/3052531
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资源简介：
The bis(nitrile) complex [Mo2Cp2(μ-SMe)3(NCCH3)2](BF4) (1) reacts with HC⋮CCPh2(OH) to give the μ-alkyne
product [Mo2Cp2(μ-SMe)3{HC⋮CCPh2(OH)}](BF4) (2). Sequential treatment with triethylamine and tetrafluoroboric acid
converts 2 almost quantitatively, via the μ-alkynyl derivative
3, into [Mo2Cp2(μ-SMe)3(μ-η1:η2-CCCPh2)] (BF4) (4), the
first example of a dinuclear μ-η1:η2-allenylidene species without
carbonyl ligands.
创建时间：
2006-10-23
