Unusual C–S Bond Cleavage in Hydro(solvo)thermal Reaction That Induces Two Novel Nickel Thiolates: The Crown [Ni16(edt)8S9(S2)]4– with an Unprecedented 12-Membered Ring System and the Cagelike [Ni13(edt)8S4(S2)2]2– with Two Distorted Cores
收藏Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Unusual_C_S_Bond_Cleavage_in_Hydro_solvo_thermal_Reaction_That_Induces_Two_Novel_Nickel_Thiolates_The_Crown_Ni_sub_16_sub_edt_sub_8_sub_S_sub_9_sub_S_sub_2_sub_sup_4_sup_with_an_Unprecedented_12_Membered_Ring_System_and_the_Cagelike_Ni_sub_13_sub_edt_sub_/2560576
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Complex 1 exhibits the crownlike structure with the unprecedented 12-membered ring system, while in 2, a cagelike cluster has been connected with two distorted cores in nickel thiolates. The synthesis of novel clusters by way of C–S bond cleavage was first reported in the field of nickel thiolates.
创建时间：
2016-02-22
