Axially Chiral Triazoloisoquinolin-3-ylidene Ligands in Gold(I)-Catalyzed Asymmetric Intermolecular (4 + 2) Cycloadditions of Allenamides and Dienes
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https://figshare.com/articles/dataset/Axially_Chiral_Triazoloisoquinolin_3_ylidene_Ligands_in_Gold_I_Catalyzed_Asymmetric_Intermolecular_4_2_Cycloadditions_of_Allenamides_and_Dienes/2490994
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资源简介：
The first highly enantioselective intermolecular (4 +
2) cycloaddition
between allenes and dienes is reported. The reaction provides good
yields of optically active cyclohexenes featuring diverse substitution
patterns and up to three stereocenters. Key to the success of the
process is the use of newly designed axially chiral N-heterocyclic carbene–gold catalysts.
创建时间：
2012-09-05
