Synthesis and Structure of a Titanium Hydrazido(2−) Complex
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https://figshare.com/articles/dataset/Synthesis_and_Structure_of_a_Titanium_Hydrazido_2_Complex/3075484
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资源简介：
Reaction of 1 equiv each of Ti(NMe2)2(dap)2 (1),
1-hexyne, tert-butyl isocyanide, and 1,1-dimethylhydrazine at
room temperature results in the formation of Ti(NNMe2)(dap)[N(But)CHCHC(Bun)N(NMe2)-κ2N] (2), where one of the ligands
is formed through iminohydrazination of the alkyne. A possible
pathway for the generation of 2 and the crystal structure of
this rare terminal hydrazido(2−) complex of titanium are
discussed.
创建时间：
2016-03-01
