The “Diindene” ArInInAr (Ar = C<sub>6</sub>H<sub>3</sub>-2,6-Dipp<sub>2</sub>, Dipp = C<sub>6</sub>H<sub>3</sub>-2,6-Pr<sup>i</sup><sub>2</sub>). Dimeric versus Monomeric In(I) Aryls: <i>p</i><i>ara</i>-Substituent Effects in Terphenyl Ligands
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The synthesis and structure of a “diindene” with significant metal−metal bonding are described. It has an In−In distance of 2.9786(5) Å, an In−In−C angle of 121.23(6)°, and an In−In bond order that is probably less than unity.
创建时间:
2016-08-18



