Orthometalated Amino-Carbene Derivatives of Iridium via Anilines and Terminal Alkynes
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https://figshare.com/articles/dataset/Orthometalated_Amino_Carbene_Derivatives_of_Iridium_via_Anilines_and_Terminal_Alkynes/2705776
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资源简介：
The reaction of a terminal alkyne (RCCH) and an aniline (R′C6H4NH2) with the dinuclear species [Cp*IrCl2]2 afforded cyclometalated amino-carbene derivatives Cp*Ir(Cl)[C(CH2R)NHC6H3R′] via a hydroamination and an orthometalation. The reaction pathway has been examined through deuterium labeling and computational studies.
创建时间：
2016-02-24
