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Double Interpenetration in a Chiral Three-Dimensional Magnet with a (10,3)‑a Structure

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https://figshare.com/articles/dataset/Double_Interpenetration_in_a_Chiral_Three_Dimensional_Magnet_with_a_10_3_a_Structure/2129830
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资源简介:
A unique chiral three-dimensional magnet with an overall racemic double-interpenetrated (10,3)-a structure of the formula [(S)-(1-PhEt)­Me3N]4[Mn4Cu6(Et2pma)12]­(DMSO)3]·3DMSO·5H2O (1; Et2pma = N-2,6-diethylphenyloxamate) has been synthesized by the self-assembly of a mononuclear copper­(II) complex acting as a metalloligand toward MnII ions in the presence of a chiral cationic auxiliary, constituting the first oxamato-based chiral coordination polymer exhibiting long-range magnetic ordering.
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2016-02-13
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