Cu(II)-Catalyzed Aerobic Hydroperoxidation of Meldrum’s Acid Derivatives and Application in Intramolecular Oxidation: A Conceptual Blueprint for O2/H2 Dihydroxylation
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https://figshare.com/articles/dataset/Cu_II_Catalyzed_Aerobic_Hydroperoxidation_of_Meldrum_s_Acid_Derivatives_and_Application_in_Intramolecular_Oxidation_A_Conceptual_Blueprint_for_O_sub_2_sub_H_sub_2_sub_Dihydroxylation/2462512
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Aerobic hydroperoxidation of Meldrum’s acid derivatives via a Cu(II)-catalyzed process is presented. The mild reaction conditions are tolerant to pendant unsaturation allowing the formation of endoperoxides via electrophilic activation. Cleavage of the O–O bond provides 1,n-diols with differentiation of the hydroxy groups.
创建时间：
2016-02-20
