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Cyclometalated Compounds. XVII. The First Threefold Cyclopalladation of a Single Benzene Ring

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NIAID Data Ecosystem2026-03-06 收录
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1,3,5-Tris(di-2-pyridylamino)benzene (1) readily undergoes reaction with palladium acetate or chloride to produce the first example of a triply cyclopalladated benzene ring. The X-ray crystal structure of the trichloro derivative 2 is described.

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2016-08-26
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