Reaction of Aryl Diazonium Salts and Diiron(I) Dithiolato Carbonyls: Evidence for Radical Intermediates
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https://figshare.com/articles/dataset/Reaction_of_Aryl_Diazonium_Salts_and_Diiron_I_Dithiolato_Carbonyls_Evidence_for_Radical_Intermediates/2528941
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资源简介：
Treatment of Fe2(pdt)(CO)4(dppv)
(1) with aryldiazonium salts affords the 34 e– adducts
[Fe2(pdt)(μ-N2Ar)(CO)4(dppv)]+ (pdt2– = 1,3-propanedithiolate, dppv = cis-C2H2(PPh2)2). Under some conditions, the same reaction gave substantial amounts
of [1]+, the product of electron transfer.
Consistent with the influence of electron transfer in the reactions
of some electrophiles with Fe(I)Fe(I) dithiolates, the reaction of
[Me3S2]+ and Fe2(pdt)(CO)4(dppbz) was found to give [Fe2(pdt)(CO)4(dppbz)]+ as well as Me2S and Me2S2 (dppbz = 1,2-bis(diphenylphosphino)benzene).
创建时间：
2012-04-23
