Inorganic-Salt-Free Reduction in Main-Group Chemistry: Synthesis of a Dibismuthene and a Distibene
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https://figshare.com/articles/dataset/Inorganic-Salt-Free_Reduction_in_Main-Group_Chemistry_Synthesis_of_a_Dibismuthene_and_a_Distibene/4765891
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资源简介：
A dibromobismuthine
and a dibromostibine that bear 4-tBu-2,6-[CH(SiMe3)2]2-C6H2 (Tbb)
groups were reduced with 2,3,5,6-tetramethyl-1,4-bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene
to afford the corresponding stable dibismuthene (TbbBiBiTbb)
and the distibene (TbbSbSbTbb), respectively. The only byproducts
obtained were easily removable tetramethylpyrazine and bromotrimethylsilane.
Importantly, inorganic salts were not generated in this reduction:
i.e., this is a unique inorganic-salt-free method for the synthesis
of compounds with multiple bonds between heavier main-group elements.
创建时间：
2017-03-20
