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Isolation and Reactivity of 1,4,2-Diazaborole

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Isolation_and_Reactivity_of_1_4_2_Diazaborole/2133058
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An isolable 1,4,2-diazaborole derivative was synthesized and structurally characterized. X-ray diffraction analysis and computational studies revealed a delocalization of 6π-electrons over the BC2N2 five-membered ring, which thus indicates the aromatic property. The reactivity toward electrophiles such as MeOTf and selectfluor was also investigated.
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2016-02-13
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