Novel Heterobimetallic Coordination of the H<sub>2</sub>B(mt)<sub>2</sub> Ligand: The Complex [Mo(SnMe<sub>2</sub>Cl)(CO)<sub>3</sub>{μ-<i>S</i>:κ<sup>3</sup>-<i>H,S,S</i><i>‘</i>-H<sub>2</sub>B(mt)<sub>2</sub>}] (mt = methimazolyl)
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资源简介：
Molybdenum stannyl complexes ligated by poly(methimazolyl)borate ligands are accessible via complementary strategies involving oxidative addition of either Ph3Sn{HB(mt)3} (mt = methimazolyl) or [Me2Sn{H2B(mt)2}]Cl to molybdenum(0) precursors or alternatively via reactions of halostannanes with the salts Na[Mo(CO)3{HxB(mt)4-x}] (x = 1, 2). One example provides a novel complex in which the H2B(mt)2 ligand bridges both molybdenum and tin, thereby providing a model for an intermediate in the oxidative addition protocol.
创建时间：
2016-05-05
