Synthesis and Characterization of Anionic, Neutral, and Cationic PNP Pincer PdII and PtII Hydrides
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The synthesis and characterization of anionic, neutral, and cationic hydride complexes of platinum and palladium are reported utilizing the PNP (PNP = 2,6-bis(di-tert-butylphosphinomethyl)pyridine) ligand. Comparisons by IR spectroscopy and X-ray crystallography are made across the series. Evaluation of the metal hydride stretching frequencies of the cationic through anionic complexes shows a trend of increasing M–H bond activation. The reactivity of these metal hydrides with oxygen is evaluated and compared to previously reported oxygen insertion reactions.
创建时间：
2016-02-17
