Hypervalent Iodine(III)-Mediated Oxidative Decarboxylation of β,γ-Unsaturated Carboxylic Acids
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https://figshare.com/articles/dataset/Hypervalent_Iodine_III_Mediated_Oxidative_Decarboxylation_of_Unsaturated_Carboxylic_Acids/2257828
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资源简介：
A novel
oxidative decarboxylation of β,γ-unsaturated
carboxylic acids mediated by hypervalent iodine(III) reagents is described.
The decarboxylative C–O bond forming reaction proceeded in
the presence of PhI(OAc)2 to give the corresponding allylic
acetates. In addition, decarboxylative C–N bond formation was
achieved by utilizing hypervalent iodine(III) reagents containing
an I–N bond. Mechanistic studies suggest the unique reactivity
of hypervalent iodine reagents in this ionic oxidative decarboxylation.
创建时间：
2016-02-16
