Chiral Cyclopropenyl Ketones: Reactive and Selective Diels–Alder Dienophiles
收藏NIAID Data Ecosystem2026-03-07 收录
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资源简介：
The synthesis and Diels–Alder reactions of cyclopropenyl ketones are described. Cyclopropenyl ketones are highly reactive dienophiles that can engage a range of cyclic dienes and 2,3-dimethylbutadiene. The strategy of using cyclopropenyl ketones to facilitate Diels–Alder reactions is not limited to products that contain three-membered rings, as reductive opening by SmI2 can be used to produce a product that lacks a cyclopropane but retains a quaternary stereogenic center.
创建时间：
2016-02-19
