A Highly Stereoselective Sequential Allylic Transfer Reaction of Diene with Diboronyl Reagent and Aldehydes Promoted by Nickel Catalyst
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https://figshare.com/articles/dataset/A_Highly_Stereoselective_Sequential_Allylic_Transfer_Reaction_of_Diene_with_Diboronyl_Reagent_and_Aldehydes_Promoted_by_Nickel_Catalyst/3266002
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资源简介：
A new protocol for the sequential allylic transfer reaction of a diene with two aldehydes in the construction of cyclic systems containing four
stereogenic centers is achieved in a one-pot operation. Reaction of the diene-alehyde 1 with aldehyde in the presence of the diboronyl reagent
catalyzed by a nickel complex produces products 2 and 3 depending on reaction conditions in high levels of diastereoselectivity. Extension
of this method to the synthesis of six-membered rings is also investigated.
创建时间：
2016-05-05
