A Highly Stereoselective Sequential Allylic Transfer Reaction of Diene with Diboronyl Reagent and Aldehydes Promoted by Nickel Catalyst
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A new protocol for the sequential allylic transfer reaction of a diene with two aldehydes in the construction of cyclic systems containing four stereogenic centers is achieved in a one-pot operation. Reaction of the diene-alehyde 1 with aldehyde in the presence of the diboronyl reagent catalyzed by a nickel complex produces products 2 and 3 depending on reaction conditions in high levels of diastereoselectivity. Extension of this method to the synthesis of six-membered rings is also investigated.
创建时间：
2016-05-05
