Amidine Dications: Isolation and [Fe]-Hydrogenase-Related Hydrogenation

Figshare2015-12-16 更新2026-04-29 收录

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Amidine Dications: Isolation and [Fe]-Hydrogenase-Related Hydrogenation

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2015-12-16

Tantallacarborane Mediated Consecutive C–C and C–N Coupling Reactions of Alkyl Isonitriles: A Facile Route to N‑Heterocycles

有机金属催化

杂环化合物构建

Reactions of tantallacarborane methyl complexes ([η1:η5-(Me2NCH2CH2)C2B9H10]TaMe3 (1) and [η1:η5-(MeOCH2CH2)C2B9H10]TaMe3 (8)) with alkyl isonitriles have been studied. Complex 1 reacted with 1 eq

Figshare2016-02-12 更新70

Osmium Models of Intermediates Involved in Catalytic Reactions of Alkylidenecyclopropanes

有机金属催化

反应中间体

The complex [OsCp{κ3-P,C,C-PiPr2[C(CH3)CH2]}(CH3CN)]PF6 (1) reacts with (2-pyridyl)methylenecyclopropane, at room temperature, to give initially the cyclobutylidene derivative [Os(η5-C5H5)(CC

NIAID Data Ecosystem60

Data for: Mechanistic insight into the rhodium-catalyzed, P-directed selective C7 arylation of indoles: a DFT study

反应机理

有机金属催化

Cartesian coordinates for all the structures involved in the artical of "mechanistic insight into the rhodium-catalyzed, P-directed selective C7 arylation of indoles: a DFT study".

NIAID Data Ecosystem20

Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex

有机金属催化

反应机理

New experimental findings suggest partial revision of the currently accepted mechanism of the carbonyl hydrosilylation catalyzed by the iridium(III) pincer complex introduced by Brookhart. Employing

NIAID Data Ecosystem60

Selective Boryl Silyl Ether Formation in the Photoreaction of Bisboryloxide/Boroxine with Hydrosilane Catalyzed by a Transition-Metal Carbonyl Complex

有机金属催化

硼烷化合物合成

Selective B–O–Si bond formation was achieved in the reaction of bisboryloxide O(Bpin)2 (pin = (OCMe2)2)/boroxine (MeBO)3 system with tertiary silane R3SiH in the presence of stoichiometric water and

NIAID Data Ecosystem60

Amidine Dications: Isolation and [Fe]-Hydrogenase-Related Hydrogenation

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