Raw Data for "A Crystalline Ylide-Stabilized Stibenium Cation"

PROJECT DESCRIPTION:<br>
With increasing interest in heavier carbene analogs and the expanding field of ylides as stabilizing substituents in main-group chemistry, we report the synthesis of the first ylide-stabilized stibenium cation 3. Despite the high electron-donating capabilities of ylide substituents, increased stabilization by sulfur handles attached to the backbone of the ylide substituents, confirmed by computational studies proved to be the key to successfully synthesizing a stable stibenium cation. Furthermore, a Sb-based lone pair is present in the HOMO, which is contradictory to previous reports on isolable stibenium cations, further showcasing the exotic nature of ylide-substituents in main-group chemistry.<br>
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DATASET DESCRIPTION:<br>
Single folders were created for all isolated compounds. Within those folders, subfolders for each experiment types (NMR, IR, CHN, Reaction-NMR) were created with the related
data within those folders. The names of the raw-data folders are in accordance with the electronic-laboratory-journal (ELN) used in the Gessner-group, with additional descriptive information, which compound and/or which reaction is contained in that folder. <br>
Programs that can be used to open the data:<br>
CHN: PDF with the measurement data were provided.<br>
IR: The data can be opened with OMNIC software (an open source alternative would be the software "OpenChrom").<br>
NMR: Can be opened with MestReNova<br>
XYZ: Can be opened with standard text editors<br>
OUT: Can be opened with standard text editors