Alcohol Amination with Aminoacidato Cp*Ir(III)-Complexes as Catalysts: Dissociation of the Chelating Ligand during Initiation
收藏NIAID Data Ecosystem2026-03-08 收录
下载链接：
https://figshare.com/articles/dataset/Alcohol_Amination_with_Aminoacidato_Cp_Ir_III_Complexes_as_Catalysts_Dissociation_of_the_Chelating_Ligand_during_Initiation/2336068
下载链接
链接失效反馈官方服务：
资源简介：
The use of aminoacidato Cp*Ir(III)-complexes
in catalytic alcohol amination reactions of primary and secondary
alcohols with amines permits to carry out these transformations at
very mild reaction conditions without the use of an additional base.
Herein we discuss the fate of the chelating aminoacidato ligands upon
initiation of Cp*Ir(III)-complexes from a mechanistic perspective.
Catalyst initiation has been followed by NMR using isotopically labeled 13C,15N-glycinato complexes.
创建时间：
2016-02-18
