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Insertion Reactions of Diazomethanes and Electrophilic Boranes

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Insertion_Reactions_of_Diazomethanes_and_Electrophilic_Boranes/2564785
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资源简介:
The electrophilic pentafluoroarylboranes B­(C6F5)3, PhB­(C6F5)2, and ClB­(C6F5)2 react with (trimethylsilyl)­diazomethane, diphenyldiazomethane, or (pentafluorophenyl)­diazomethane, affording insertion into the one or two B–C bonds in a facile and high-yielding route to the boranes (Me3SiCH­(C6F5))­B­(C6F5)2, (Me3SiCH­(C6F5))2B­(C6F5), (Me3SiCH­(C6F5))­(Me3SiCH­(Ph))­B­(C6F5), (C6F5)­ClB­(CPh2(C6F5)), and (C6F5)2B­(CH­(C6F5)2).
创建时间:
2016-02-22
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