Upside Down! Crystallographic and Spectroscopic Characterization of an [Fe<sup>IV</sup>(O<sub>syn</sub>)(TMC)]<sup>2+</sup> Complex
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FeII(TMC)(OTf)2 reacts with 2-tBuSO2–C6H4IO to afford an oxoiron(IV) product, 2, distinct from the previously reported [FeIV(Oanti)(TMC)(NCMe)]2+. In MeCN, 2 has a blue-shifted near-IR band, a higher ν(FeO), a larger Mössbauer quadrupole splitting, and quite a distinct 1H NMR spectrum. Structural analysis of crystals grown from CH2Cl2 reveals a complex with the formulation of [FeIV(Osyn)(TMC)(OTf)](OTf) and the shortest FeIVO bond [1.625(4) Å] found to date.
创建时间：
2016-02-12
