Copper-Catalyzed Enantioselective Intramolecular N‑Arylation, an Efficient Method for Kinetic Resolutions
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Copper_Catalyzed_Enantioselective_Intramolecular_i_N_i_Arylation_an_Efficient_Method_for_Kinetic_Resolutions/2394853
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资源简介：
For the first time, copper-catalyzed intramolecular N-arylation was successfully applied to the kinetic resolution strategy. Under the catalysis of CuI–BINOL derived ligands, the kinetic resolution of rac-2-amino-3-(2-iodoaryl)propionates and rac-2-amino-4-(2-iodoaryl)butanoates afforded chiral intramolecular coupling products and recovered the starting materials in high enantioselectivity (s factors up to 245).
创建时间：
2016-02-19
