Photochemical Synthesis of a Stable Terminal Uranium(VI) Nitride
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https://figshare.com/articles/dataset/Photochemical_Synthesis_of_a_Stable_Terminal_Uranium_VI_Nitride/13162791
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资源简介：
Terminal uranium nitrides have so
far proven impossible to isolate
by photolysis of azides. Here we report the second ever example of
an isolated terminal uranium(VI) nitride. We show that the terminal
nitride [NBu4][U(OSi(OtBu)3)4(N)], 3, can be prepared upon photolysis with
UV light of the U(IV) azide analogue. This is achieved by careful
tailoring of the azide precursor and of the reaction conditions. Complex 3 is stable under ambient conditions but reacts readily with
electrophiles (H+ and CO).
创建时间：
2020-10-29
