Origin of the Diastereoselection in the Indium-Mediated Addition of Haloallylic Sulfones to Aldehydes
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https://figshare.com/articles/dataset/Origin_of_the_Diastereoselection_in_the_Indium_Mediated_Addition_of_Haloallylic_Sulfones_to_Aldehydes/3230593
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资源简介：
The R1 substituents at C(2) of the haloallylic sulfones 1 play a pivotal role in controlling the diastereoselectivity of the indium-mediated
addition reaction to benzaldehyde to produce the homoallylic alcohols 3. The R1 Me group of 1 prefers the chair form in the In-coordinated
six-membered cyclic transition state to give anti-3a, and the R1 Ph group of 1 favors the twist boat form to give syn-3n, both in a high 13:1
selectivity.
创建时间：
2006-03-30
