Synthesis and Magnetic Properties of Wheel-Shaped [Mn<sub>12</sub>] and [Fe<sub>6</sub>] Complexes
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The reactions of the ligands N-methyldiethanol amine and N-ethyldiethanol amine (abbreviated H2mdea and H2edea, respectively) with [Mn12O12(O2CCH3)16(H2O)4] yield novel dodecanuclear wheel-shaped products. The capability of the ligands H2mdea and H2edea to support wheel structures in metals other than Mn is demonstrated with the crystal structure of a new hexanuclear ferric wheel.
创建时间：
2004-10-18
