Hydride Attack on a Coordinated Ferric Nitrosyl: Experimental and DFT Evidence for the Formation of a Heme Model–HNO Derivative
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https://figshare.com/articles/dataset/Hydride_Attack_on_a_Coordinated_Ferric_Nitrosyl_Experimental_and_DFT_Evidence_for_the_Formation_of_a_Heme_Model_HNO_Derivative/2057847
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资源简介：
Heme–HNO species
are crucial intermediates in several biological
processes. To date, no well-defined Fe heme–HNO model compounds
have been reported. Hydride attack on the cationic ferric [(OEP)Fe(NO)(5-MeIm)]OTf
(OEP = octaethylporphyrinato dianion) generates an Fe–HNO product
that has been characterized by IR and 1H NMR spectroscopy.
Results of DFT calculations reveal a direct attack of the hydride
on the N atom of the coordinated ferric nitrosyl.
创建时间：
2015-12-23
