Selective Catalytic Synthesis of α‑Alkylated Ketones and β‑Disubstituted Ketones via Acceptorless Dehydrogenative Cross-Coupling of Alcohols
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https://figshare.com/articles/dataset/Selective_Catalytic_Synthesis_of_Alkylated_Ketones_and_Disubstituted_Ketones_via_Acceptorless_Dehydrogenative_Cross-Coupling_of_Alcohols/13623117
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资源简介：
Herein, a phosphine-free pincer ruthenium(III)
catalyzed β-alkylation
of secondary alcohols with primary alcohols to α-alkylated ketones
and two different secondary alcohols to β-branched ketones are
reported. Notably, this transformation is environmentally benign and
atom efficient with H2O and H2 gas as the only
byproducts. The protocol is extended to gram-scale reaction and for
functionalization of complex vitamin E and cholesterol derivatives.
创建时间：
2021-01-21
